Leszek Niedzicki - pliki dla studentow

Witam na stronie Leszka Niedzickiego. / Welcome to Leszek Niedzicki's site. Konsultacje (kliknij by rozszerzyć) / Consultations (click to expand)

W roku akademickim 2024/2025 - konsultacje poprzez Teams - bez umawiania się, proszę po prostu zadawać pytania, będę odpowiadał na bieżąco, w miarę możliwości czasowych. In the academic year 2024/2025 - consultations through Teams - no need to register or book, just ask questions through the chat, I will answer as soon as possible, depending on my schedule. Odbywają się tylko po uprzednim umówieniu się na nie (przez Teams/mail/osobiście). Pokój 346, Gmach Chemii, środy g. 13:15 i czwartki g.15:15. Inne terminy tylko po kontakcie mailowym minimum dwa dni wcześniej. Jeśli nikt nie przychodzi przez 15 minut, to uznaję, że nikt nie przyjdzie. Only upon appointment made personally/by Teams/mail. Room no. 346, Chemistry building (central campus), Wednesdays 1:15pm and Thursdays 3:15pm. Other days/hours possible upon contact with me. If no one comes for 15 minutes, consultations can be cancelled.

Jak do mnie trafić? (kliknij by rozszerzyć) / How to reach me? (click to expand)

Wejście z terenu centralnego (od fontanny): Z holu windowego wjechać windą na 3. piętro (lub skorzystać ze schodów z szatni). Na 3. piętrze, wychodząc z windy należy skręcić w lewo, dojść do końca korytarza, wejść na półpiętro i zadzwonić przez domofon do drzwi po prawej (drzwi nr 341): domofon nr 6, ew. jeśli nikt nie odbiera, to 1, 7 lub 10. Po otwarciu drzwi trzeba iść na wprost przez całe laboratorium. 346 to pierwszy pokój po lewej w korytarzu za laboratorium. Entrance from the campus side (fountain): In the elevator hall use elevator to reach 3. floor (or use stairs from the cloakroom entrance). On the 3. floor, when going out of the elevator turn left, go to the end of the corridor and 10 steps up at the end of the corridor. Use intercom on the right at the door number 341. Dial 6, in case nobody picks up you can also try 1, 7 or 10. Behind the doors with intercom go straight through the laboratory. 346 is the first door on the left in the corridor behind the laboratory.

Kontakt mailowy: leszek.niedzicki(skasuj-to)@pw.edu.pl, skresl (skasuj-to) / delete (skasuj-to). Scopus ID: 22941405200 ResearcherID: AAY-9057-2020

Articles by Leszek Niedzicki on new salts for electrolytes (particularly for Li-ion cells) (click to expand)

1.) The first published data on LiTDI, LiPDI and LiHDI salts as PEG500DME-based electrolytes L. Niedzicki*, M. Kasprzyk, K. Kuziak, G.Z. Żukowska, M. Armand, M. Bukowska, M. Marcinek, P. Szczeciński, W. Wieczorek, Modern generation of polymer electrolytes based on lithium conductive imidazole salts J. Power Sources 192 (2009) 612-617. DOI: 10.1016/j.jpowsour.2009.03.050 2.) Chronologically the first data on LiTDI, LiPDI and LiHDI - synthesis route, full spectroscopic and NMR characterization of salts, their electrochemical stability in PC and PEO (SPE), stability against aluminium and thermal stability data L. Niedzicki*, G.Z. Żukowska, M. Bukowska, P. Szczeciński, S. Grugeon, S. Laruelle, M. Armand, S. Panero, B. Scrosati, M. Marcinek, W. Wieczorek, New type of imidazole based salts designed specifically for lithium ion batteries Electrochim. Acta 55 (2010) 1450-1454. DOI: 10.1016/j.electacta.2009.05.008 3.) Performance of LiTDI, LiPDI and LiHDI as PC-based electrolytes - ionic conductivity, lithium cation transference numbers, stability vs lithium metal over time, ionic associations L. Niedzicki*, M. Kasprzyk, K. Kuziak, G.Z. Żukowska, M. Marcinek, W. Wieczorek, M. Armand, Liquid electrolytes based on new lithium conductive imidazole salts J. Power Sources 196 (2011) 1386-1391. DOI: 10.1016/j.jpowsour.2010.08.097 4a.) Ionic associations in PEO, AN, PC and other solvents studied by Raman spectroscopy compared with DFT calculations results 4b.) Supplemental Information J. Scheers*, L. Niedzicki, G.Z. Żukowska, P. Johansson, W. Wieczorek, P. Jacobsson, Ion-ion and ion-solvent interactions in lithium imidazolide electrolytes studied by Raman spectroscopy and DFT models Phys. Chem. Chem. Phys. 13 (2011) 11136-11147. DOI: 10.1039/c1cp20063a 5.) LiTDI, LiPDI and LiDCTA salts performance in EC-DMC(50/50)-based electrolytes, ionic conductivity at 1M concentration comparison with other salts, thermal stability, electrochemical stability, half-cell cycling performance, rate capability compared with LiPF₆ L. Niedzicki, S. Grugeon, S. Laruelle, P. Judeinstein, M. Bukowska, J. Prejzner, P. Szczecinski, W. Wieczorek, M. Armand*, New covalent salts of the 4+ V class for Li batteries J. Power Sources 196 (2011) 8696-8700. DOI: 10.1016/j.jpowsour.2011.06.030 6a.) X-ray diffraction crystal structure studies of LiTDI, LiPDI and LiHDI crystallized from acetonitrile 6b.) Supplemental Information M. Dranka*, L. Niedzicki, M. Kasprzyk, M. Marcinek, W. Wieczorek, J. Zachara An insight into coordination ability of dicyanoimidazolato anions toward lithium in presence of acetonitrile. Crystal structures of novel lithium battery electrolyte salts Polyhedron 51 (2013) 111-116. DOI: 10.1016/j.poly.2012.12.022 7.) [LINK to Publisher - Elsevier] TDI anion performance and physicochemical properties as ionic liquid constituent - used for separation applications M. Zawadzki*, L. Niedzicki, W. Wieczorek, U. Domanska Estimation of extraction properties of new imidazolide anion based ionic liquids on the basis of activity coefficient at infinite dilution measurements Sep. Purif. Technol. 118 (2013) 242-254. DOI: 10.1016/j.seppur.2013.07.006 8.) LiTDI concentration in EC-based electrolytes optimized for the best ionic conductivity and lithium cation transference number L. Niedzicki*, E. Karpierz, A. Bitner, M. Kasprzyk, G.Z. Zukowska, M. Marcinek, W. Wieczorek Optimization of the lithium-ion cell electrolyte composition through the use of the LiTDI salt Electrochim. Acta 117C (2014) 224-229. DOI: 10.1016/j.electacta.2013.11.134 9.) Li3BTI (LiTDI trimeric salt) synthesis route, spectroscopic and NMR characterization, thermal and electrochemical stability, ionic conductivity and lithium cation transference number measured in PC and EC:DMC-based electrolytes, as well as cycling with anode and cathode in half-cells. T. Trzeciak, L. Niedzicki*, G. Groszek, P. Wieczorek, M. Marcinek, W. Wieczorek New trivalent imidazole-derived salt for lithium-ion cell electrolyte J. Power Sources 252C (2014) 229-234. DOI: 10.1016/j.jpowsour.2013.12.018 10.) TDI-based ionic liquids - EMImTDI, PMImTDI, BMImTDI - characterized by XRD, TGA, NMR, CV, as well as range of LiTDI solutions in these ILs characterized for their conductivity, lithium cation transference number and CV L. Niedzicki*, E. Karpierz, M. Zawadzki, M. Dranka, M. Kasprzyk, A. Zalewska, M. Marcinek, J. Zachara, U. Domanska, W. Wieczorek Lithium cation conducting TDI anion-based ionic liquids Phys. Chem. Chem. Phys. 16 (2014) 11417-11425. DOI: 10.1039/c3cp55354j 11.) LiTDI concentration in EC:EMC-based electrolytes optimized for the best ionic conductivity and lithium cation transference number with cycling in a half-cell with an advanced anode material L. Niedzicki*, B. Brzozowski, P. Wieczorek LiTDI and solvent mixture based electrolytes for lithium-ion cells Electrochim. Acta 174 (2015) 625-629. DOI: 10.1016/j.electacta.2015.06.038 12.) LiTDPI (TDI analog with imidazopyrazine two-ring skeleton) synthesis route, spectroscopic and NMR characterization, thermal and electrochemical stability, ionic conductivity and lithium cation transference number measured in PC and EC:DMC-based electrolytes, as well as cycling with graphite anode in a half-cell. L. Niedzicki*, J. Korczak, A. Bitner, M. Bukowska, P. Szczecinski An imidazopyrazine-derived anion for lithium conducting electrolyte application RSC Adv. 5 (2015) 101917-101922. DOI: 10.1039/c5ra15869a 13.) LiTDPI (TDI analog with benzimidazole two-ring skeleton) synthesis route, spectroscopic and NMR characterization, thermal and electrochemical stability, ionic conductivity and lithium cation transference number measured in PC and EC:DMC-based electrolytes, as well as cycling with graphite anode in a half-cell. Supplemental Information L. Niedzicki*, P. Oledzki, A. Bitner, M. Bukowska, P. Szczecinski Benzimidazole-derived anion for lithium-conducting electrolytes J. Power Sources 306 (2016) 573-577. DOI: 10.1016/j.jpowsour.2015.12.006 14.) Optimization of LiTDI-EC:DMC-based electrolytes with VC and FEC additives and cycling with silicon-carbon (50:50) composite anodes, showing much better performance than LiPF₆ L. Niedzicki*, P. Oledzki, P. Wieczorek, M. Marcinek, W. Wieczorek LiTDI based lithium-ion cells electrolyte compositions Synth. Met. 223 (2017) 73-79. DOI: 10.1016/j.synthmet.2016.12.005 15.) Investigation of LiTDI and LiPDI - comparison of differences in association and solvation in triglyme solutions performed with FTIR, viscosity, conductivity, lithium cation transference number and ionic fractions M. Broszkiewicz*, A. Zalewska, L. Niedzicki Comparison of LiTDI and LiPDI salts and influence of their perfluoroalkyl side-chain on association and electrochemical properties in triglyme Ionics 25 (2019) 3651-3660. DOI: 10.1007/s11581-019-02905-w 16.) Review on TDI and other Huckel-type anions - a success story M. Armand, P. Johansson, M. Bukowska, P. Szczecinski, L. Niedzicki*, M. Marcinek, M. Dranka, J. Zachara, G. Zukowska, M. Marczewski, G. Schmidt, W. Wieczorek* Review - Development of Hückel type anions: from molecular modeling to industrial commercialization. A success story J. Electrochem. Soc. 167 (2020) 070562. DOI: 10.1149/1945-7111/ab829c 17a.) LiHDI (LiTDI analog) additive for stabilizing SEI layer, particularly for higher temperatures 17b.) Supplemental Information M. Broszkiewicz*, B. Brzozowski, T. Trzeciak, A. Zalewska, J. Ryl, L. Niedzicki* Imidazole-based lithium salt LiHDI as a solid electrolyte interphase-stabilising additive for lithium-conducting electrolytes Molecules 29 (2024) 804. DOI: 10.3390/molecules29040804 18a.) Investigation of LiTDI and LiPDI - comparison of differences in association and solvation in diglyme and tetraglyme solutions 18b.) Supplemental Information M. Broszkiewicz*, A. Zalewska, E. Karpierz-Marczewska, L. Niedzicki Comparison of trifluoromethyl- and pentafluoroethyl-substituted dicyanoimidazolide lithium salts - their association and electrochemical properties in oligo(ethylene glycols) of different chain length J. Mol. Liq. 400 (2024) 124550. DOI: 10.1016/j.molliq.2024.124550 19a.) Fluorine-free LiPCP salt tested with sustainable cathodes - made of abundant materials (LFP or LMFP) in water-based process 19b.) Supplemental Information C. Limachi*, K. Rogala, M. Broszkiewicz, M. Cabello, L. Niedzicki*, M. Armand, W. Wieczorek Development of fluorine-free electrolytes for aqueous-processed olivine-type phosphate cathodes Molecules 29 (2024) 4698. DOI: 10.3390/molecules29194698

Instrukcje do cwiczen laboratoryjnych (Wydział Chemiczny): Zastosowanie formalizmu Fuossa-Krausa do szacowania asocjacji jonowej ((c) by Leszek Niedzicki) Wyznaczanie liczb przenoszenia kationow litowych ((c) by Leszek Niedzicki) Spektroskopia Impedancyjna (EIS) ((c) by Leszek Niedzicki)
Laboratorium syntezy, charakteryzacji i przetwórstwa materiałów funkcjonalnych: Podstawy impedancyjnych metod badania materiałów - wstęp teoretyczny ((c) by Leszek Niedzicki) Podstawy impedancyjnych metod badania materiałów - analiza danych i zastosowania ((c) by Marta Kasprzyk) Podstawy impedancyjnych metod badania materiałów - opis ustawień pomiarowych ((c) by Marta Kasprzyk)